Product ID:REGULAR UNLEADED AUTOMOTIVE GASOLINE
MSDS Date:02/01/1990
FSC:9130
NIIN:00-148-7102
MSDS Number: BMZQH

CENEX/LAND O LAKES AG SERVICES

NW 9087
MINNEAPOLIS, MN 55485-9087
US

Emergency Phone: 612-451-5151/800-424-9300(CHEMTREC)

Info Phone: 612-451-5151

Cage: KO281

CENEX/LAND O'LAKES AG SERVICES

64089 ST PAUL, MN 55164-0089 US

Telephone: 612-451-5151

Cage: 0LMC0

1,2,4-TRIMETHYLBENZENE (SARA III)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: < 12%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9192

HYDROCARBONS (AROMATIC & PARAFFINIC)

Fraction By Weight: 50-80% %

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: < 5%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 1 - 3%

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CYCLOHEXANE (SARA III)

CAS: 110-82-7

RTECS: GU6300000

Fraction By Weight: < 2%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM, 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CUMENE (SARA III)

CAS: 98-82-8

RTECS: GR8575000

Fraction By Weight: < 2%

OSHA PEL S, 50 PPM

ACGIH TLV: S, 50 PPM; 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 10-15%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 10-20% %

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: < 15%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LD50 LC50 Mixture:NOT SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INHALATION CAUSES INTENSE BURNING OF
MUCOUS MEMBRANES, THROAT AND RESPIRATORY TRACT, BRONCHOPNEUMONIA,
PULMONAY EDEMA. REPEATED OR PROLONGED SKIN CONTACT CAUSES
DERMATITIS, BLISTERING OF THE SKIN, DEF ATTING. EYE CONTACT MAY
CAUSE HYPEREMIAOF THE CONJUNCTIVA. INGESTION MAY CAUSE CENTRAL
NERVOUS SYSTEM DISTURBANCES.
Explanation of Carcinogenicity:THIS PRODUCT CONTAINS BENZENE WHICH IS
LISTED AS A CARCINOGEN BY NTP, IARC AND OSHA.
Effects of Overexposure:BURNING OF MUCOUS MEMBRANES, THROAT,
RESPIRATORY TRACT, BRONCHOPNEUMONIA, PULMONAY EDEMA, DERMATITIS,
SKIN BLISTERING, DEFATTING, INEBRIATION, DROWSINESS, BLURRED
VISION, VERTIGO, CONFUSION, VOMITING, UNCONSCIOUSNESS,
CONVULSIONS, CYANOSIS. ASPIRATION HAZARD.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN CONDITIONS MAY BE
AGGRAVATED BY EXPOSURE.

First Aid:EYES: FLUSH THOROUGHLY WITH WATER FOR 15 MINUTES INCLUDING
UNDER EYELIDS. CALL A PHYSICIAN. SKIN: REMOVE CONTAMINATED
CLOTHING. WASH EFFECTED AREA WITH SOAP AND WATER. IF IRRITATION
DEVELOPS, CALL A P HYSICIAN. INHALTION: REMOVE TO FRESH AIR.
RESSTORE BREATHING AND ADMINISTER OXYGEN IF NEEDED. INGESTION: DO
NOT INDUCE VOMITING! CONTACT A PHYSICIAN. NEVER GIVE ANYTHING BY
MOUTH IF UNCONSCIOUS.

Flash Point Method:TCC
Flash Point:-50F,-46C
Lower Limits:1.4 %
Upper Limits:7.6 %
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, ALCOHOL FOAM
Fire Fighting Procedures:USE OF WATER MAY BE INEFFECTIVE TO EXTINGUISH
FIRE, BUT USE WATER SPRAY TO COOL FIRE EXPOSED DRUMS AND TANKS.
FIRE-FIGHTERS SHOULD WEAR SCBA AND PROTECTIVE GEAR
Unusual Fire/Explosion Hazard:VAPORS CAN FLOW ALONG SURFACES, REACH
DISTANT IGNITION SOURCES AND FLASH BACK. CAN REACT VIOLENTLY WITH
OXIDIZING AGENTS.

Spill Release Procedures:REPORT SPILLS AS REQUIRED. REMOVE SOURCES OF
HEAT OR IGNITION. PROVIDE ADEQUATE VENTILATION. CLEAN-UP PERSONNEL
REQUIRE PROTECTION AGAINST LIQUID CONTACT AND VAPOR INHALATION.
CONTAIN SPILL. DO NOT AL LOW TO ENTER SEWER OR SURFACE WATER. ADD
ABSORBENT
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN CLOSED CONTAINERS IN A COOL,
DRY, WELL-VENTILATED AREA AWAY FROM SOURCES OF HEAAT, IGNITION AND
STRONG OXIDIZING AGENTS.
Other Precautions:PROTECT CONTAINERS FROM PHYSICAL DAMAGE. AVOID DIRECT
SUNLIGHT. OUTDOOR OR DETACHED STORAGE PREFERRED. NO SMOKING IN
AREAS OF USE. PREVENT STATIC ELECTRIC SPARKS AND USE
EXPLOSION-PROOF ELECTRICAL SER VICES. AVOID SKIN CONTACT.

Respiratory Protection:APPROPRIATE NIOSH RESPIRATOR SHOULD BE AVIALABLE
FOR NON-ROUTINE OR EMERGENCY USE ABOVE THE TLV.
Ventilation:USE GENERAL AND LOCAL EXHAUST VENTILATION (EXPLOSION-PROOF)
TO KEEP VAPORS BELOW THE TLV REQUIREMENTS IN THE WORKPLACE.
Protective Gloves:RUBBER GLOVES
Eye Protection:CHEMICAL SAAFETY GOGGLES OR FACESHIELD
Other Protective Equipment:RUBBER BOOTS, CLOTHING TO BE CHANGED DAILY
AND LAUNDERED. EYEWASH FOUNTAINS, SHOWERS AND WASHING FACILITIES.
Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT
AND BEFORE EATING DRINKING OR SMOKING.
Supplemental Safety and Health
PROVIDE SUITABLE TRAINING TO THOSE HANDLING AND WORKING WITH THIS
MATERIAL. AVOID INHALATION OF VAPORS. INDOOR USE OF THIS MATERIAL
REQUIRES EXHAUST VENTILATION TO REMOVE VAPORS.

HCC:F2
Boiling Pt:B.P. Text:80.0F,26.7C
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Pres:275-475
Vapor Density:3.0 - 4.0
Spec Gravity:0.65-0.75
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR, MOBILE LIQUID WITH A CHARACTERISTIC GASOLINE
ODOR
Percent Volatiles by Volume:100 %

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Stability Condition to Avoid:SPARKS, IGNITION SOURCES, OPEN FLAMES
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
HYDROCARBONS

Waste Disposal Methods:BURN SCRAP MATERIAL IN AN APPROVED INCINERATOR.
BURN CONTAMINATED IQUID BY SPRAYING INTO AN INCINERATOR. DISPOSE IN
ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.